Rice University Researchers in Houston Take a Giant Leap forward around Industrial-scale Manufacturing with Carbon Nanotubes

November 3, 2009

Wik

Carbon-based nano-materials are on track to becoming a foundation for economic growth for the 21st century.  And the United States could be in the driver’s seat of this age of Carbon Capitalism and rethinking of carbon-based Industrialism!

Manufacturing Eras: Silicon to Carbon
If the 20th century economic revolution of computer-based information technologies was shaped by humankind’s ability to manipulate silicon-based materials, the next fifty years of wealth creation and productivity gains will almost certainly be built upon the material foundation of carbon-carbon bonds.

Carbon nanotubes are long chains of carbon-carbon bonds that were discovered and synthesized in the early 1990s.  Their performance properties equate to a ‘holy grail’ of sorts for materials scientists and engineers.  Single-walled carbon nanotubes (SWNTs) are more than 100 times stronger than steel and more flexible.  Mixing carbon nanotubes with plastics could lead to a manufacturing era of strong cheap materials to replace steel and aluminum used in aerospace – automotive industries and building construction.  Designing and building vehicles made of carbon nanotube (CNT) composite plastics would require less energy during manufacturing, improve vehicle fuel efficiencies through a much lighter chassis, and improve safety by reducing the crushing weight in a collision without sacrificing strength and protection.

Beyond tensile strength, carbon nanotube-plastic composite materials promise an era of plastic materials with electrochemical properties.  Depending on how the carbon bonds are aligned (e.g. chirality) they can behave like a conductive metal, or (if the bonds are turned in the opposite direction) nanotubes repel electrons.  Combine the two and you have a semiconductor that surpasses the performance of silicon and other precious metals.

Carbon nanotube plastic composites that conduct electricity would create tremendous value for manufacturers of airplanes, consumer electronics (e.g. thin flexible display screens) and the energy industry (e.g. plastic solar cells, batteries, fuel cells).

So what’s the problem?

Until now, scientists have had trouble mixing carbon nanotubes into liquids that are the foundation of industrial scale plastic manufacturing based on fluid techniques.  Carbon nanotubes are ‘sticky’ and tend to clump up when dissolved into liquids that are used in making plastic products.

Now, Houston-based researchers at Rice University have advanced a method for dissolving large amounts of single-walled carbon nanotubes (SWNTs) into a chlorosulfonic acid-based  solvent that is ‘compatible with high throughput manufacturing techniques.’ If we can continue to evolve methods for liquid-based manufacturing techniques that use the power of carbon nanotubes, the world could fundamentally re-write the 21st century Industrial Age.

Plastics and nanotubes derived from natural gas (or other carbon rich biomass) might someday compete with steel as the foundation for industrial materials manufacturing.   Large steel and aluminum plants could be replaced with smaller, less capital and energy intensive polymer-composite plants.   Emerging economies could set up advanced material manufacturing operations based on more cost effective hydrocarbons rather than iron ore and precious metals.

The economic and environmental benefits are enormous – and the potential revival of US composite manufacturing could help to reverse years of decline in traditional iron ore based US Industrial Belt economies that have been unable to compete against China.   These regions might find a new value proposition in the global economy by focusing on a era of manufacturing based on CNT-plastics.

YouTube: Carbon Nanotube fibre dissolving in chlorosulfonic acid
Matteo Pasquali‘s group at Rice University

Image credit: Wikimedia (Carbon Nanotube) CC License

Links to story on Nanowerk


{ 2 comments… read them below or add one }

Human December 3, 2009 at 6:50 am

DO they decompose …? a simple plastic bag doesnt decompose for decades and how is world going to handle carbon nano tubes…hmm

Garry Golden December 5, 2009 at 5:48 pm

Human: Yes, this is an important question!

There are different types of plastics (also known as polymers- long repeating chains of molecules) that have different ‘breakdown’ properties. In most cases like plastic bags we have been moving towards polymer chains that breakdown easily. But your hard plastic cases (consumer electronics) are another story and we really need to just contain these materials in waste landfills. (There is also a difference between ‘not breaking down’ and ‘toxic’.) So nanoparticles can be used in bio-materials that are degradable and non-toxic – or non biodegradable materials (‘nano’ or otherwise).

There is still much to be learned about nanoparticles in the world’s natural ecosystems and human body. But our knowledge on the full life cycle of nanostructured compounds is actually quite extensive given intentional studies that have been in existence for over a fifteen years now. (Scientists have been asking these tough questions for many years and it is front of mind for research and regulators. In addition, we have decades of knowledge related to hydrocarbon polymers.

In most cases we are talking about nanotubes and nanoparticles made of inert (non-toxic) elements and compounds. And these nanotubes are likely to be part of larger structured compounds that already exist in our world.

I’m quite aware of concerns raised by ‘nano’ materials skeptics but most of these folks tend to just be skeptical of everything and I think the fears are usually overblown.

The end game is to move towards bio-compatible synthetic materials that allow us to create abundance without damaging the planet. Carbon-carbon bonds and carbon-hydrogen bonds are a great way to meet growing demands for material goods. And tapping the structural and material property benefits of nanotechnology is likely to be the era that enables that type of sustainable growth.

Thanks for your email! Hope that answers your question..! You can find many studies on the web if you are more interested.

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